Multilayer ceramic capacitor including first and second outer layer portions and an inner layer portion disposed therebetween

ABSTRACT

A multilayer body includes an inner layer portion, and a first outer layer portion and a second outer layer portion with the inner layer portion therebetween. The inner layer portion includes a conductive layer arranged closest to a first principle surface side to a conductive layer arranged closest to a second principle surface side in a stacking direction. The first outer layer portion includes a first dielectric layer arranged closest to the first principle surface side. The second outer layer portion includes an outer portion including a second dielectric layer arranged closest to the second principle surface side and an inner portion including a first dielectric layer arranged next to the outer portion at the first principle surface side.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to multilayer ceramic capacitors, multilayer ceramic capacitor arrays, and multilayer ceramic capacitor mounted bodies.

2. Description of the Related Art

Japanese Unexamined Patent Application Publication No. 2012-248581 discloses a multilayer ceramic capacitor that suppresses the occurrence of cracks. In the multilayer ceramic capacitor described in Japanese Unexamined Patent Application Publication No. 2012-248581, a base body includes an inner electrode multilayer body (inner layer portion) in which a first inner electrode and a second internal electrode are stacked so as to face each other with a dielectric therebetween; and a first dielectric multilayer body (outer layer) and a second dielectric multilayer body (outer layer) that sandwich the inner electrode multilayer body (inner layer portion) from both sides thereof in a stacking direction. Further, the first dielectric multilayer body (outer layer) including a first base body principal surface is formed so as to be thicker than the second dielectric multilayer body (outer layer) including a second base body principal surface in the stacking direction.

SUMMARY OF THE INVENTION

Modes of how cracks occur include a mode in which an outer stress is applied to a dielectric layer of the multilayer ceramic capacitor and causes a crack to occur therein. The outer stress is produced when a substrate on which a multilayer ceramic capacitor is mounted is subjected to an external force.

The inventors of the present invention discovered another mode of the occurrence of cracks. In this mode, the inventors discovered that an inner stress is produced due to a difference in thermal contraction rates between the dielectric layer and the conductive layer at the time of firing of the multilayer ceramic capacitor, and this inner stress is applied to a boundary between the inner layer portion and the outer layer portion and causes a crack to occur (delamination).

In the multilayer ceramic capacitor described in Japanese Unexamined Patent Application Publication No. 2012-248581, the occurrence of cracks caused by the external stress is significantly reduced or prevented, however, no consideration is given with regard to suppression of the occurrence of cracks caused by the internal stress produced due to the difference in thermal contraction rates between the dielectric layer and the conductive layer.

Accordingly, preferred embodiments of the present invention provide a multilayer ceramic capacitor capable of significantly reducing or preventing cracks caused by internal stress produced due to a difference in thermal contraction rates between the dielectric layer and the conductive layer.

A multilayer ceramic capacitor based on a first aspect of various preferred embodiments of the present invention includes a multilayer body including a plurality of dielectric layers and a plurality of conductive layers, which are stacked therein, and including a first principle surface and a second principle surface that are arranged so as to be opposite to each other in a stacking direction; and a pair of outer electrodes provided on portions of a surface of the multilayer body and electrically connected to at least one of the plurality of conductive layers. The multilayer body is further provided with a first end surface and a second end surface that are arranged at opposite sides of the multilayer body while connecting the first principle surface and the second principle surface, and a first side surface and a second side surface that are arranged at opposite sides of the multilayer body while connecting the first principle surface and the second principle surface as well as the first end surface and the second end surface. The multilayer body further includes an inner layer portion and a first outer layer portion and a second outer layer portion with the inner layer portion therebetween, the inner layer portion including, of the plurality of conductive layers, a conductive layer arranged closest to the first principle surface side to a conductive layer arranged closest to the second principle surface side in the stacking direction. In the inner layer portion, the plurality of conductive layers and a partial set of the plurality of dielectric layers are stacked. Of the plurality of dielectric layers, the first outer layer portion includes a dielectric layer arranged closest to the first principle surface side. The second outer layer portion includes an outer portion and an inner portion. Of the plurality of dielectric layers, the outer portion includes a dielectric layer arranged closest to the second principle surface side, and the inner portion includes a dielectric layer arranged next to the outer portion at the first principle surface side. Each one of the plurality of dielectric layers preferably contains barium titanate as a primary component and Si as an accessory component. The materials of the dielectric layer of the outer portion have a higher Si composition ratio relative to Ti, compared to the materials of the dielectric layers included in the inner layer portion and the dielectric layer of the inner portion. A boundary portion between the outer portion and the inner portion has a larger Si content compared to a middle portion of the outer portion.

In the present application, the term “Si composition ratio relative to Ti” indicates a value of Si mol/Ti mol, and the Si content can be recognized by element mapping, for example.

In a preferred embodiment of the present invention, the second outer layer portion preferably is thicker than the first outer layer portion.

In a preferred embodiment of the present invention, the inner portion preferably is thicker than the first outer layer portion.

In a preferred embodiment of the present invention, a thickness of the inner layer portion in the stacking direction preferably is larger than a width of the conductive layer nearest to the second outer layer portion.

In a preferred embodiment of the present invention, the pair of outer electrodes preferably are provided on at least portions of the second principle surface of the multilayer body. A top layer portion of the outer portion on the second principle surface side preferably has a higher Si content compared to a middle portion of the outer portion.

In a preferred embodiment of the present invention, the materials of the partial set of dielectric layers included in the inner layer portion preferably have a higher rare earth element composition ratio relative to Ti, compared to the materials of the dielectric layer of the outer portion.

In the present application, the term “rare earth composition ratio relative to Ti” indicates a value of rare earth mol/Ti mol.

In a preferred embodiment of the present invention, the rare earth element composition ratio relative to Ti in the materials of the partial set of dielectric layers included in the inner layer portion preferably is about 0.003 or more, and the rare earth element composition ratio relative to Ti in the materials of the dielectric layer of the outer portion preferably is less than about 0.003, for example.

In a preferred embodiment of the present invention, the materials of the dielectric layers included in the inner layer portion, the dielectric layer included in the first outer layer portion, and the dielectric layer of the inner portion preferably have a higher Mn composition ratio relative to Ti, compared to the materials of the dielectric layer of the outer portion.

In the present application, the term “Mn composition ratio relative to Ti” indicates a value of Mn mol/Ti mol.

In a preferred embodiment of the present invention, the Mn composition ratio relative to Ti in the materials of the dielectric layers included in the inner layer portion, the dielectric layer included in the first outer layer portion, and the dielectric layer of the inner portion preferably is about 0.0008 or more, and the Mn composition ratio relative to Ti in the materials of the dielectric layer of the outer portion preferably is about 0.0008 or less, for example.

A multilayer ceramic capacitor based on a second aspect of various preferred embodiments of the present invention includes a multilayer body including a plurality of dielectric layers and a plurality of conductive layers, which are stacked therein, and including a first principle surface and a second principle surface that are arranged so as to be opposite to each other in a stacking direction; and a pair of outer electrodes provided on portions of a surface of the multilayer body and electrically connected to at least a partial set of the plurality of conductive layers. The multilayer body is further provided with a first end surface and a second end surface connecting the first principle surface and the second principle surface and arranged at opposite sides of the multilayer body, and a first side surface and a second side surface connecting the first principle surface and the second principle surface as well as the first end surface and the second end surface and arranged at opposite sides of the multilayer body. The multilayer body further includes an inner layer portion and a first outer layer portion and a second outer layer portion with the inner layer portion therebetween, the inner layer portion including, of the plurality of conductive layers, a conductive layer arranged closest to the first principle surface side to a conductive layer arranged closest to the second principle surface side in the stacking direction. In the inner layer portion, the plurality of conductive layers and a partial set of the plurality of dielectric layers are stacked. A thickness of the inner layer portion in the stacking direction is larger than a width of the conductive layer nearest to the second outer layer portion, in a direction connecting the first side surface and the second side surface with a minimum distance. Of the plurality of dielectric layers, the first outer layer portion includes a dielectric layer arranged closest to the first principle surface side. The second outer layer portion includes an outer portion and an inner portion. Of the plurality of dielectric layers, the outer portion is defined by a dielectric layer arranged closest to the second principle surface side, and the inner portion is defined by a dielectric layer arranged next to the outer portion at the first principle surface side. A thickness of the outer portion is equal to or larger than a thickness of the inner portion in the stacking direction. Each one of the plurality of dielectric layers contains barium titanate as a primary component and Si as an accessory component. The materials of the dielectric layer of the outer portion have a higher Si composition ratio relative to Ti, compared to the materials of the dielectric layers included in the inner layer portion and the dielectric layer of the inner portion.

In a preferred embodiment of the present invention, the second outer layer portion preferably is thicker than the first outer layer portion.

In a preferred embodiment of the present invention, a thickness of the inner layer portion in the stacking direction preferably is larger than a width of the multilayer body in a direction connecting the first side surface and the second side surface with a minimum distance.

In a preferred embodiment of the present invention, a boundary portion of the outer portion with the inner portion preferably has a larger Si content compared to a middle portion of the outer portion.

In a preferred embodiment of the present invention, the pair of outer electrodes preferably are provided on at least portions of the second principle surface of the multilayer body. A top layer portion of the outer portion on the second principle surface side preferably has a larger Si content compared to a middle portion of the outer portion.

In a preferred embodiment of the present invention, the thickness of the outer portion preferably is about 30 μm or more, for example.

In a preferred embodiment of the present invention, the thickness of the inner portion preferably is about 20 μm or more, for example.

In a preferred embodiment of the present invention, the materials of the partial set of dielectric layers included in the inner layer portion preferably have a higher rare earth element composition ratio relative to Ti, compared to the materials of the dielectric layer of the outer portion.

In a preferred embodiment of the present invention, the materials of the dielectric layers included in the inner layer portion, the dielectric layer included in the first outer layer portion, and the dielectric layer of the inner portion preferably have a higher Mn composition ratio relative to Ti, compared to the materials of the dielectric layer of the outer portion.

A multilayer ceramic capacitor array based on a third aspect of various preferred embodiments of the present invention includes a plurality of multilayer ceramic capacitors according to one of the foregoing preferred embodiments, an elongated carrier tape in which a plurality of depressed portions are provided at intervals to respectively store the plurality of multilayer ceramic capacitors, and a packaging body including a cover tape configured to cover the plurality of depressed portions by attaching to the carrier tape. The plurality of multilayer ceramic capacitors is stored inside respective ones of the plurality of depressed portions in such a way that the second principle surface is disposed on a bottom side of each depressed portion.

A multilayer ceramic capacitor mounted body based on a fourth aspect of various preferred embodiments of the present invention includes a multilayer ceramic capacitor according to one of the foregoing preferred embodiments and a component-receiving body on which the multilayer ceramic capacitor is mounted. The multilayer ceramic capacitor is mounted on the component-receiving body in such a way that the second principle surface is disposed on the component-receiving body side.

Various preferred embodiments of the present invention, and modifications and combinations thereof, significantly reduce or prevent the occurrence of cracks caused by the internal stress produced due to the difference in thermal contraction rates between the dielectric layer and the conductive layer.

The above and other elements, features, steps, characteristics and advantages of the present invention will become more apparent from the following detailed description of the preferred embodiments with reference to the attached drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a perspective view illustrating an exterior of a multilayer ceramic capacitor according to preferred embodiment 1 of the present invention.

FIG. 2 is a cross sectional view of the multilayer ceramic capacitor of FIG. 1 viewed from a line II-II arrow direction.

FIG. 3 is a cross sectional view of the multilayer ceramic capacitor of FIG. 1 viewed from a line III-III arrow direction.

FIG. 4 is a cross sectional view of the multilayer ceramic capacitor of FIG. 2 viewed from a line IV-IV arrow direction.

FIG. 5 is a cross sectional view of the multilayer ceramic capacitor of FIG. 2 viewed from a line V-V arrow direction.

FIG. 6 is a flowchart illustrating a fabrication method of multilayer ceramic capacitor according to the preferred embodiment 1 of the present invention.

FIG. 7 is an exploded perspective view illustrating a multilayer structure of a sheet group unit that forms a partial multilayer body before formation of an outer portion of a multilayer ceramic capacitor according to the preferred embodiment 1 of the present invention.

FIG. 8 is a cross sectional view illustrating a state where a mother sheet group is being pressure-bonded.

FIG. 9 is a cross sectional view illustrating a state where a mother sheet group pressured-bonded at step S15 and a plurality of second ceramic green sheets are being pressure-bonded.

FIG. 10 is a cross sectional view illustrating a structure of a multilayer ceramic capacitor mounted body according to the preferred embodiment 1 of the present invention.

FIG. 11 is a plan view illustrating a structure of a multilayer ceramic capacitor array according to the preferred embodiment 1 of the present invention.

FIG. 12 is a cross sectional view of the multilayer ceramic capacitor array of FIG. 11 viewed from a line XII-XII arrow direction.

FIG. 13 is a cross sectional view illustrating a state where a mother sheet group of a multilayer ceramic capacitor according to preferred embodiment 2 of the present invention is being pressure-bonded.

FIG. 14 is a cross sectional view illustrating a halfway state where a mother sheet group and a plurality of second ceramic green sheets are being pressure-bonded.

FIG. 15 is a cross sectional view illustrating a state where a mother multilayer body is cut.

FIG. 16 is a schematic view illustrating a state where a substrate on which a multilayer ceramic capacitor is mounted is bent in exemplary experiment 2.

FIG. 17 is a view illustrating an example of a magnified image of a cross section of a multilayer ceramic capacitor observed with a scanning electron microscope.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

A multilayer ceramic capacitor, a multilayer ceramic capacitor array including the multilayer ceramic capacitor, and a multilayer ceramic capacitor mounted body according to respective preferred embodiments of the present invention are described below with reference to the drawings. In the description of preferred embodiments below, the same reference numerals are assigned to the same or corresponding portions in the drawings, and description thereof will not be repeated.

Preferred Embodiment 1

FIG. 1 is a perspective view illustrating an exterior of a multilayer ceramic capacitor according to the preferred embodiment 1 of the present invention. FIG. 2 is a cross sectional view of the multilayer ceramic capacitor of FIG. 1 viewed from a line II-II arrow direction. FIG. 3 is a cross sectional view of the multilayer ceramic capacitor of FIG. 1 viewed from a line III-III arrow direction. FIG. 4 is a cross sectional view of the multilayer ceramic capacitor of FIG. 2 viewed from a line IV-IV arrow direction. FIG. 5 is a cross sectional view of the multilayer ceramic capacitor of FIG. 2 viewed from a line V-V arrow direction. In FIGS. 1 to 5, L denotes a lengthwise direction of a multilayer body which will be described below, W denotes a widthwise direction of the multilayer body, and T denotes a thickness direction of the multilayer body.

As illustrated in FIGS. 1 to 5, a multilayer ceramic capacitor 10 according to the preferred embodiment 1 of the present invention includes a multilayer body 11 and a pair of outer electrodes 14. The multilayer body 11 includes a plurality of dielectric layers 12 and a plurality of conductive layers 13, which are stacked on each other, and is provided with a first principle surface 111 and a second principle surface 112 that are arranged opposite to each other in a stacking direction. The pair of outer electrodes 14 is provided at portions of the surface of the multilayer body 11 and is electrically connected to all the conductive layers 13.

The stacking direction of the dielectric layers 12 and the conductive layers 13 is perpendicular or substantially perpendicular to the lengthwise direction L of the multilayer body 11 and the widthwise direction W of the multilayer body 11. In other words, the stacking direction of the dielectric layers and the conductive layers 13 is parallel or substantially parallel to the thickness direction T of the multilayer body 11.

The multilayer body 11 further includes a first end surface 113 and a second end surface 114 that connect the first principle surface 111 and the second principle surface 112 and are arranged at opposite sides of the multilayer body 11. The multilayer body 11 still further includes a first side surface 115 and a second side surface 116 that connect the first principle surface 111 and the second principle surface 112, connect the first end surface 113 and the second end surface 114, and are arranged at opposite sides of the multilayer body 11. A minimum distance between the first side surface 115 and the second side surface 116 is less than a minimum distance between the first end surface 113 and the second end surface 114. In other words, a measurement W₀ of the multilayer body 11 in the widthwise direction W is less than a dimension of the multilayer body 11 in the lengthwise direction L. Externally the multilayer body 11 preferably has a cuboid or substantially cuboid shape, for example. Alternatively, the corner portion or the ridge portion or both of the multilayer body 11 may be rounded.

The multilayer body 11 includes an inner layer portion 11 m, and a first outer layer portion 12 b ₁ and a second outer layer portion 12 b ₂ with the inner layer portion 11 m located therebetween. The inner layer portion 11 m includes, of the plurality of conductive layers 13, a conductive layer 13 arranged closest to the first principle surface 111 side to a conductive layer 13 arranged closest to the second principle surface 112 side in the stacking direction of the multilayer body 11.

The plurality of dielectric layers 12 includes a plurality of first dielectric layers 12 x and a second dielectric layer 12 y, which preferably include ceramic green sheets containing different materials from each other, which will be described below.

The first outer layer portion 12 b ₁ includes, of the plurality of dielectric layers 12, a first dielectric layer 12 x arranged closest to the first principle surface 111 side. The second outer layer portion 12 b ₂ includes an outer portion 12 b ₂₂ and an inner portion 12 b ₂₁. The outer portion 12 b ₂₂ preferably includes the second dielectric layer 12 y, which is one of the plurality of dielectric layers 12, arranged closest to the second principle surface 112 side. The inner portion 12 b ₂₁ preferably includes a first dielectric layer 12 x arranged next to the outer portion 12 b ₂₂ at the first principle surface 111 side. Here, the configuration of the first outer layer portion 12 b ₁ is not limited to the foregoing one. Alternatively, the first outer layer portion 12 b ₁ may include an outer portion and an inner portion wherein the outer portion preferably includes the second dielectric layer 12 y, which is one of the plurality of dielectric layers 12, arranged closest to the first principle surface 111 side, and the inner portion preferably includes a first dielectric layer 12 x that is arranged next to the outer portion at the second principle surface 112 side.

In the inner layer portion 11 m, a partial set of the plurality of dielectric layers 12 x and all the conductive layers 13 are stacked in such a way that the first dielectric layers 12 x and the conductive layers 13 are stacked on top of each other in an alternating fashion. In other words, the inner layer portion 11 m includes all the conductive layers 13. Each conductive layer preferably has a rectangular or substantially rectangular shape in planar view.

In the present preferred embodiment, all the conductive layers 13 are electrically connected to the pair of outer electrodes 14, but it is not limited thereto. In another preferred embodiment, at least a partial set of the plurality of conductive layers 13 may be electrically connected to the pair of outer electrodes 14. In other words, the plurality of conductive layers 13 may include a conductive layer 13 that is not electrically connected to the pair of outer electrodes 14.

The pair of outer electrodes 14 is provided at both sides of the multilayer body 11 in the lengthwise direction L. Specifically, one of the pair of outer electrodes 14 is provided at the first end surface 113 side of the multilayer body 11 in the lengthwise direction L, and the other outer electrode 14 is provided at the second end surface 114 side of the multilayer body 11 in the lengthwise direction L. In the present preferred embodiment, one of the pair of outer electrodes 14 is preferably arranged so as to extend from the first end surface 113 to the first principle surface 111, the second principle surface 112, the first side surface 115, and the second side surface 116. The other outer electrode 14 is preferably arranged so as to extend from the second end surface 114 to the first principle surface 111, the second principle surface 112, the first side surface 115, and the second side surface 116. The arrangement of the pair of outer electrodes 14 is, however, not limited to the foregoing one. A different arrangement may be used as long as the pair of outer electrodes 14 is disposed on portions of the surface of the multilayer body 11, has electrical connections with at least some of the plurality of conductive layers 13, and makes it possible the multilayer ceramic capacitor 10 to be mounted.

One of the pair of outer electrodes 14 is connected to a partial set of the plurality of conductive layers 13 at the first end surface 113. The other outer electrode 14 is connected to the remaining set of the plurality of conductive layers 13 at the second end surface 114. The partial set of the conductive layers 13 and the remaining set of the conductive layers 13 are stacked in alternating fashion so as to face each other in the inner layer portion 11 m with the first dielectric layer 12 x therebetween.

As illustrated in FIG. 3, a thickness T₁ of the inner layer portion 11 m in the stacking direction of the multilayer body 11 is larger than a width measurement W₁ of the inner layer portion 11 m, in which the plurality of conductive layers 13 are present, in the widthwise direction W of the multilayer body 11, which is a direction connecting the first side surface 115 and the second side surface 116 with a minimum distance. The thickness T₁ of the inner layer portion 11 m in the stacking direction of the multilayer body 11 preferably is larger than the width measurement W₀ of the multilayer body 11 in the direction connecting the first side surface 115 and the second side surface 116 with the minimum distance.

Preferably, a thickness h₂₂ of the outer portion 12 b ₂₂ is equal to or larger than a thickness h₂₁ of the inner portion 12 b ₂₁. Preferably, the thickness h₂₂ of the outer portion 12 b ₂₂ is about 30 μm or more, for example, as will be described below. Preferably, the thickness h₂₁ of the inner portion 12 b ₂₁ is about 20 μm or more, for example, as will be described below.

In the present preferred embodiment, the second outer layer portion 12 b ₂ is thicker than the first outer layer portion 12 b ₁. In other words, a thickness h₂ of the second outer layer portion 12 b ₂ is larger than a thickness h₁ of the first outer layer portion 12 b ₁. The inner portion 12 b ₂₁ is thicker than the first outer layer portion 12 b ₁. In other words, the thickness h₂₁ of the inner portion 12 b ₂₁ is larger than the thickness h₁ of the first outer layer portion 12 b ₁. Alternatively, the thickness h₂₁ of the inner portion 12 b ₂₁ may be equal to or less than the thickness h₁ of the first outer layer portion 12 b ₁, for example.

A thickness T₀ of the multilayer body 11 in the stacking direction of the multilayer body 11 preferably is equal or substantially equal to a sum of the thickness T₁ of the inner layer portion 11 m, the thickness h₁ of the first outer layer portion 12 b ₁, and the thickness h₂ of the second outer layer portion 12 b ₂.

Preferably, in the widthwise direction of the multilayer body 11, a maximum measurement of side gaps 12 c, which are gaps between the inner layer portion 11 m and respective ones of the first side surface 115 and the second side surface 116, is larger than the thickness h₁ of the first outer layer portion 12 b ₁, as will be described below. More preferably, an average measurement ((W₀−W₁)/2) of the side gaps 12 c is larger than the thickness h₁ of the first outer layer portion 12 b ₁. Still more preferably, the maximum measurement or the average measurement ((W₀−W₁)/2) of the side gaps 12 c is larger than about 30 μm and less than about 90 μm, for example Further, the maximum measurement of the side gap 12 c is preferably larger than the thickness h₂₁ of the inner portion 12 b ₂₁.

Next, each element of the multilayer ceramic capacitor 10 is described in detail.

A metal such as Ni, Cu, Ag, Pd, Au, or the like, or an alloy including at least one of the foregoing metals such as, for example, an alloy of Ag and Pd or the like may be used as a material for forming each layer of the plurality of conductive layers 13. Preferably, the thicknesses of each layer of the plurality of conductive layers 13 is not less than about 0.3 μm and not more that about 2.0 μm after firing, for example.

Each one of the pair of outer electrodes 14 preferably includes a base layer preferably arranged so as to cover one of two end portions of the multilayer body 11 and a plated layer provided so as to cover this base layer. As a material for forming the base layer, a metal such as Ni, Cu, Ag, Pd, Au, or the like, or an alloy including at least one of the foregoing metals such as, for example, an alloy of Ag and Pd or the like may be used. Preferably, the thickness of the base layer is not less than about 10.0 μm and not more than about 50.0 μm, for example.

The base layer may be formed by using a method in which electrically conductive paste is baked after being applied on both end portions of the multilayer body 11 that has been subjected to firing or a method in which electrically conductive paste applied on both end portions of the multilayer body 11 before firing is baked together with the conductive layers 13. Alternatively, the base layer may be formed by using a method in which both end portions of the multilayer body 11 are plated or a method in which electrically conductive resin including thermoset resin is cured after being applied on both end portions of the multilayer body 11.

In the case that the base layer is formed from the electrically conductive resin, a load applied to the multilayer body 11 due to an external stress, which is produced when a component-receiving body on which the multilayer ceramic capacitor 10 is mounted is bent by an external force, may be reduced, and the occurrence of cracks in the multilayer body 11 is significantly reduced or prevented. Thus, making the second outer layer portion 12 b ₂ thicker and forming the pair of outer electrodes 14 from the electrically conductive resin achieve further reduction or prevention of the occurrence of cracks in the multilayer body 11.

As a material for forming the plated layer, a metal such as Sn, Ni, Cu, Ag, Pd, Au, or the like, or an alloy including at least one of the foregoing metals such as, for example, an alloy of Ag and Pd or the like may be used.

The plated layer may include a plurality of layers, for example. In this case, it is preferable that the plated layer has a double layer structure in which a Sn plated layer is provided on a Ni plated layer. The Ni plated layer defines and serves as a solder barrier layer. The Sn plated layer has excellent solderablity. Preferably, the thickness of the plated layer at each layer is not less than about 1.0 μm and not more than about 10.0 μm, for example.

Each layer of the plurality of dielectric layers 12 preferably includes, as a primary component, a perovskite type compound that is represented as ABO₃ where A contains Ba, B contains Ti, and O is oxygen. In other words, each layer of the second dielectric layer 12 y and the plurality of the first dielectric layers 12 x preferably includes BaTiO₃, barium titanate, as the primary component.

Further, each layer of the plurality of dielectric layers 12 preferably includes Si as an accessory component. Si is contained as the accessory component by adding glass or a Si compound such as SiO₂ or the like to the primary component, namely, the perovskite type compound represented as ABO₃. In addition, a Mn compound, a Mg compound, a Co compound, a Ni compound, a rare earth compound or the like may be added to the primary component, namely, the perovskite type compound represented as ABO₃.

The materials of the second dielectric layer 12 y of the outer portion 12 b ₂₂ have a higher Si composition ratio relative to Ti, compared to the materials of each one of a partial set of the first dielectric layers 12 x included in the inner layer portion 11 m, the first dielectric layer 12 x of the first outer layer portion 12 b ₁, and the first dielectric layer 12 x of the inner portion 12 b ₂₁. The Si composition ratio as well as other constituent's composition ratios may be expressed as the molar ratio. In the following description, the composition ratio is expressed as the molar ratio. The molar ratio of Si relative to Ti at each layer of the plurality of dielectric layers 12 may be measured by using a wavelength-dispersive X-ray spectrometer (WDX).

Preferably, the molar ratio of Si relative to Ti in the materials of the second dielectric layer 12 y of the outer portion 12 b ₂₂ is not less than about 0.013 and not larger than about 0.03, for example. In the case where the molar ratio of Si relative to Ti in the materials of the second dielectric layer 12 y of the outer portion 12 b ₂₂ is not less than about 0.013 and not larger than about 0.03, the reliability of the outer portion 12 b ₂₂ may become lower.

The molar ratio of Si relative to Ti in the materials of the second dielectric layer 12 y of the outer portion 12 b ₂₂ is higher preferably by about 0.004 or more, and more preferably about 0.008 or more, for example, compared to the molar ratio of Si relative to Ti in the materials of the first dielectric layer 12 x forming the inner portion 12 b ₂₁.

A boundary portion 12 z of the outer portion 12 b ₂₂ with the inner portion 12 b ₂₁ has a larger Si content compared to a middle portion 12 m of the outer portion 12 b ₂₂. Further, a top layer portion 12 s of the outer portion 12 b ₂₂ on the second principle surface 112 side has a larger Si content compared to the middle portion 12 m of the outer portion 12 b ₂₂. The boundary portion 12 z and the top layer portion 12 s having larger Si content in the outer portion 12 b ₂₂ may each be identified from element mapping performed with a field emission wavelength-dispersive X-ray spectrometer (FE-WDX).

Next, a non-limiting example of a fabrication method of the multilayer ceramic capacitor 10 according to the present preferred embodiment is described.

FIG. 6 is a flowchart illustrating a non-limiting example of a fabrication method of multilayer ceramic capacitor according to the preferred embodiment 1 of the present invention. The fabrication method of multilayer ceramic capacitor described below is a method in which the multilayer ceramic capacitors 10 are mass-produced simultaneously. In this method, a mother multilayer body is fabricated by performing batch processing up to a midway stage of the fabrication process, subsequently the mother multilayer body is cut into individual pieces, and then soft multilayer bodies obtained after the cutting are subjected to another processing to obtain a plurality of the multilayer ceramic capacitors 10.

As illustrated in FIG. 6, when fabricating the multilayer ceramic capacitor 10, a first ceramic slurry is prepared first (step S11). Specifically, ceramic powder, binder, solvent, and the like are mixed at a predetermined mixture ratio to form the first ceramic slurry.

Next, a first ceramic green sheet is formed (step S12). Specifically, the first ceramic green sheet is produced by forming the first ceramic slurry into a sheet shape on a carrier film by using a die coater, a gravure coater, a microgravure coater, or the like.

Next, a mother sheet is formed (step S13). Specifically, the mother sheet in which a predetermined electrically conductive pattern is provided on the first ceramic green sheet is formed by printing an electrically conductive paste on the first ceramic green sheet so as to form a predetermined pattern by using a screen printing method or a gravure printing method or the like.

The mother sheet to be manufactured is now described. FIG. 7 is an exploded perspective view illustrating a multilayer structure of a sheet group unit that forms a partial multilayer body before formation of an outer portion of a multilayer ceramic capacitor according to the preferred embodiment 1 of the present invention.

As illustrated in FIG. 7, a partial multilayer body 11 p is fabricated by using as a constituent material a sheet group unit including a plurality of unit sheets 120 a, 130 a, and 130 b, whose structures are different from each other. More specifically, the partial multilayer body 11 p is fabricated by stacking these plural unit sheets 120 a, 130 a, and 130 b whose structures are different from each other in a predetermined order and then subjecting them to pressure-bonding and firing.

The unit sheet 120 a preferably includes only a ceramic base material 12 xr and has no electrically conductive pattern is formed on its top surface. The unit sheet 120 a becomes a portion that forms the first dielectric layer 12 x of the inner portion 12 b ₂₁ or the first outer layer portion 12 b ₁ after firing.

The unit sheets 130 a and 130 b are each formed in such a way that an electrically conductive pattern 13 r having a predetermined shape is formed on the top surface of the ceramic base material 12 xr. The electrically conductive patterns 13 r of the unit sheets 130 a and 130 b become portions that form the conductive layers 13 of the inner layer portion 11 m after firing. Further, the ceramic base material 12 xr of the unit sheets 130 a and 130 b become portions that form the first dielectric layers 12 x of the inner layer portion 11 m after firing.

The mother sheet has a layout in which a plurality of unit sheets having the same or substantially the same shape is arranged to form a planar array. Here, each unit sheet forms a unit block therein and corresponds to each one of the unit sheets 130 a and 130 b illustrated in FIG. 7.

Here, the unit sheet 130 a and the unit sheet 130 b preferably have the same or substantially the same shape. Thus, mother sheets having the same or substantially the same electrically conductive pattern may be used as the mother sheets including the unit sheets 130 a and the unit sheets 130 b. The multilayer structure of the unit sheets 130 a and 130 b illustrated in FIG. 7 may be obtained by stacking the mother sheets having the same or substantially the same electrically conductive pattern while displacing each mother sheet by the amount of a half pitch during a stacking process of the mother sheets, which will be described below.

In addition to the mother sheets having the electrically conductive pattern 13 r, the first ceramic green sheets that are fabricated without going through the step S13 are also prepared as the mother sheets.

Next, the mother sheets are stacked (step S14). Specifically, stacking a plurality of the mother sheets according to a predetermined rule allows the unit blocks to be arranged in such a way that each unit block has the multilayer structure illustrated in FIG. 7 in the stacking direction within a mother sheet group after stacking.

Next, the mother sheet group is pressure-bonded (step S15). FIG. 8 is a cross sectional view illustrating a state where the mother sheet group is being pressure-bonded. FIG. 8 illustrates only a portion that corresponds to one of partial multilayer bodies 11 p. As illustrated in FIG. 8, in the present preferred embodiment, a plurality of the mother sheets forming the first outer layer portion 12 b ₁, a plurality of the mother sheets forming the inner layer portion 11 m, and a plurality of the mother sheets forming the inner portion 12 b ₂₁ are stacked in this order to form the mother sheet group.

The mother sheet group placed on a base 90 is being compressed and pressure-bonded by pressing a die plate 91 from the side of the mother sheets that form the inner portion 12 b ₂₁ in the stacking direction of the mother sheet group as denoted by an arrow 92.

Next, a second ceramic slurry is prepared (step S21). Specifically, ceramic power, binder, solvent, and the like are mixed at a predetermined mixture ratio to form the second ceramic slurry. Compared to the first ceramic slurry, more Si is added to the second ceramic slurry.

Next, a second ceramic green sheet is formed (step S22). Specifically, the second ceramic green sheet is produced by forming the second ceramic slurry into a sheet shape on a carrier film by using a die coater, a gravure coater, a microgravure coater, or the like.

Next, a plurality of the second ceramic green sheets is stacked on the mother sheet group that is pressure-bonded at step S15 (step S23). Specifically, a plurality of the second ceramic green sheets is stacked on the mother sheets forming the inner portion 12 b ₂₁. The second ceramic green sheet preferably includes only a ceramic base material 12 yr that forms the second dielectric layer 12 y of the outer portion 12 b ₂₂. Alternatively, instead of stacking the plurality of the second ceramic green sheets including only the ceramic base material 12 yr, a paste containing the second ceramic slurry may be applied over the mother sheet forming the inner portion 12 b ₂₁.

Next, the mother sheet group that is pressure-bonded at step S15 and the plurality of the second ceramic green sheets are pressure-bonded (step S24). FIG. 9 is a cross sectional view illustrating a state where the mother sheet group pressured-bonded at step S15 and the plurality of the second ceramic green sheets are being pressure-bonded. FIG. 9 illustrates only a portion that corresponds to a one of soft multilayer bodies 11 q. As illustrated in FIG. 9, the mother sheet group that is pressure-bonded at step S15 and the plurality of the second ceramic green sheets are being compressed and pressure-bonded by pressing down the die plate 91 from the side of the mother sheets of the outer portion 12 b ₂₂ along the stacking direction of the mother sheet group as denoted by the arrow 92. This completes the fabrication of the mother multilayer body.

Next, the mother multilayer body is cut (step S25). Specifically, the mother multilayer body is cut by shearing or dicing to separate in columns and rows, thus cutting into soft multilayer bodies 11 q.

Next, firing of the soft multilayer bodies 11 q is performed (step S26). Specifically, the soft multilayer bodies 11 q that are cut out are heated up to a predetermined temperature to perform firing of ceramic dielectric materials and an electrically conductive material. The firing temperature may be set in response to types of the ceramic dielectric materials and the electrically conductive material. For example, the firing temperature may be set in a range from about 900 degrees C. to about 1300 degrees C. inclusive.

Next, barrel finishing of the soft multilayer bodies 11 q is performed (step S27). Specifically, the soft multilayer bodies 11 q after firing are sealed in a small box called a barrel with a media ball having a higher hardness compared to ceramic materials, and this barrel is being tumbled to polish the soft multilayer bodies 11 q. This makes it possible to provide curved roundness at the outer surfaces (particularly at corner portions and ridge portions) of the soft multilayer bodies 11 q, and completes the formation of the multilayer body 11.

Next, the outer electrodes are formed (step S28). Specifically, a metal film is formed by painting an electrically conductive paste at an end portion of a portion of the multilayer body 11, which includes the first end surface 113, and at an end portion of another portion of the multilayer body 11, which includes the second end surface 114. Further, after these metal films are subjected to firing, the metal films are subjected to Ni plating and Sn plating in sequence. This completes the formation of a pair of outer electrodes 14 on the outer surface of the multilayer body 11.

A series of the foregoing steps makes possible the fabrication of the multilayer ceramic capacitor 10 having the structure illustrated in FIGS. 1 to 5.

In the multilayer ceramic capacitor 10 according to the present preferred embodiment, the materials of the second dielectric layer 12 y of the outer portion 12 b ₂₂ preferably have a higher molar ratio of Si relative to Ti, compared to the materials of each one of the partial set of the first dielectric layers 12 x included in the inner layer portion 11 m and the first dielectric layer 12 x of the inner portion 12 b ₂₁. In other words, the outer portion 12 b ₂₂ includes more Si than the inner portion 12 b ₂₁. The dielectric layer having a larger Si content has a higher thermal contraction rate at the time of firing. Thus, at the time of firing, the thermal contraction rate of the outer portion 12 b ₂₂ is larger than that of the inner portion 12 b ₂₁. As a result, the thermal contraction rate of the outer portion 12 b ₂₂ approaches the thermal contraction rate of the conductive layer 13 in the inner layer portion 11 m.

Accordingly, in the multilayer ceramic capacitor 10, the internal stress is alleviated that is caused by a difference in thermal contraction ratio between the conductive layer and the dielectric layer at the time of firing and that is applied to the boundary between the inner layer portion 11 m and the second outer layer portion 12 b ₂. This significantly reduces or prevents the occurrence of cracks (delamination) at the boundary between the inner layer portion 11 m and the second outer layer portion 12 b ₂.

In the case where the molar ratio of Si relative to Ti in the materials of the second dielectric layer 12 y of the outer portion 12 b ₂₂ preferably is higher by about 0.004 or more, compared to that of the first dielectric layer 12 x of the inner portion 12 b ₂₁, the occurrence of cracks (delamination) is effectively reduced or prevented at the boundary between the inner layer portion 11 m and the second outer layer portion 12 b ₂. Further, in the case where this molar ratio preferably is higher by about 0.008 or more, the occurrence of cracks (delamination) is more effectively reduced or prevented at the boundary between the inner layer portion 11 m and the second outer layer portion 12 b ₂.

When the thickness of the outer portion 12 b ₂₂ is equal to or larger than that of the inner portion 12 b ₂₁ as described in the above, the effects of the stress alleviation caused by the thermal contraction of the outer portion 12 b ₂₂ may reach the boundary between the inner layer portion 11 m and the second outer layer portion 12 b ₂ more easily.

When the thickness h₂₂ of the outer portion 12 b ₂₂ is about 30 μm or more, a contraction force that is equal to or larger than a required value may be secured. The contraction force acts on the inner portion 12 b ₂₁ due to the thermal contraction of the outer portion 12 b ₂₂.

When the thickness h₂₁ of the inner portion 12 b ₂₁ is about 20 μm or more, dispersion of Si contained in the outer portion 12 b ₂₂ into the inner layer portion 11 m is significantly reduced or prevented. When the Si content at the inner layer portion 11 m becomes too large, grain growth of ceramic particles advances too far at the time of firing in the first dielectric layer 12 x included in the inner layer portion 11 m, and voltage endurance of the first dielectric layer 12 x decreases. As a result, the inner layer portion 11 m becomes prone to short circuit. Thus, in the case where the thickness h₂₁ of the inner portion 12 b ₂₁ is about 20 μm or more, the voltage endurance of the first dielectric layer 12 x included in the inner layer portion 11 m is maintained, and the occurrence of short circuit is significantly reduced or prevented.

As described above, the thickness h₂₁ of the inner portion 12 b ₂₁ is larger than the thickness h₁ of the first outer layer portion 12 b ₁. As will be described below, the boundary portion 12 z of the outer portion 12 b ₂₂ with the inner portion 12 b ₂₁ improves a sticking force between the outer portion 12 b ₂₂ and the inner portion 12 b ₂₁. Therefore, even if the inner portion 12 b ₂₁ is made somewhat thicker, the occurrence of cracks (delamination) is significantly reduced or prevented at the boundary between the outer portion 12 b ₂₂ and the inner portion 12 b ₂₁. Accordingly, the contraction force due to the thermal contraction of the outer portion 12 b ₂₂ is allowed to act on the inner portion 12 b ₂₁. This makes it possible to alleviate the internal stress applied to the boundary between the inner layer portion 11 m and the inner portion 12 b ₂₁ due to the difference in thermal contraction ratio between the conductive layer and the dielectric layer at the time of firing, and significantly reduce or prevent the occurrence of cracks (delamination) at the boundary between the inner layer portion 11 m and the second outer layer portion 12 b ₂.

As described above, the maximum measurement of the side gap 12 c is preferably larger than the thickness h₁ of the first outer layer portion 12 b ₁. In the case where the first outer layer portion 12 b ₁ is made thinner, the internal stress, which acts on the boundary between the inner layer portion 11 m and the first outer layer portion 12 b ₁ due to the difference in thermal contraction ratio between the conductive layer and the dielectric layer at the time of firing, is alleviated. This makes it possible to significantly reduce or prevent the occurrence of cracks (delamination) at the boundary between the inner layer portion 11 m and the first outer layer portion 12 b ₁. In the case where the thickness h₂₁ of the inner portion 12 b ₂₁ is about 20 μm or more, the dispersion of Si contained in the outer portion 12 b ₂₂ into the inner layer portion 11 m is significantly reduced or prevented. In the case where the Si content at the inner layer portion 11 m becomes too large, the grain growth of ceramic particles advances too far at the time of firing in the first dielectric layer 12 x included in the inner layer portion 11 m, and the voltage endurance of the first dielectric layer 12 x decreases. As a result, the inner layer portion 11 m becomes prone to short circuits. Thus, in the case where the thickness h₂₁ of the inner portion 12 b ₂₁ is about 20 μm or more, the voltage endurance of the first dielectric layer 12 x included in the inner layer portion 11 m preferably is maintained, and the occurrence of short circuit is significantly reduced or prevented.

On the other hand, in the case where the maximum measurement of the side gap 12 c is made larger, it becomes easier to apply load pressure to a plurality of the first dielectric layers 12 x present at the side gaps 12 c at the time of pressure bonding the mother sheet group. This improves adhesiveness among the first dielectric layers 12 x present at the side gaps 12 c. As a result, the occurrence of cracks (delamination) is significantly reduced or prevented at the first dielectric layers 12 x present at the side gaps 12 c.

As described above, the average measurement ((W₀−W₁)/2) of the side gaps 12 c is more preferably larger than the thickness h₁ of the first outer layer portion 12 b ₁. The average measurement ((W₀−W₁)/2) of the side gaps 12 c corresponds to one half of a sum of adjacent side gaps 12 c that belong to two multilayer bodies lying next to each other when the mother multilayer body is cut into individual multilayer bodies. Thus, in the case where the average measurement ((W₀−W₁)/2) of the side gaps 12 c is made larger than the thickness h₁ of the first outer layer portion 12 b ₁, it becomes easier to apply load pressure to a plurality of the first dielectric layers 12 x present at the side gaps 12 c at the time of pressure bonding the mother sheet group. This improves the adhesiveness among the first dielectric layers 12 x present at the side gaps 12 c. As a result, the occurrence of cracks (delamination) is significantly reduced or prevented at the first dielectric layers 12 x present at the side gaps 12 c. In other words, both the suppression effects against the occurrence of short circuit in the inner layer portion 11 m and the occurrence of cracks (delamination) are achieved in a more stable manner even in the case where the dimension of the side gap 12 c at the first side surface 115 side differs from the dimension of the side gap 12 c at the second side surface 116 side.

As described above, the maximum measurement of the side gaps 12 c is preferably larger than the thickness h₂₁ of the inner portion 12 b ₂₁. In the case where the inner portion 12 b ₂₁ is made thinner, it becomes easier to allow the contraction force due to the thermal contraction of the outer portion 12 b ₂₂ to act on the inner portion 12 b ₂₁. This makes it possible to alleviate the internal stress applied to the boundary between the inner layer portion 11 m and the inner portion 12 b ₂₁ due to the difference in thermal contraction ratio between the conductive layer and the dielectric layer at the time of firing, and significantly reduce or prevent the occurrence of cracks (delamination) at the boundary between the inner layer portion 11 m and the second outer layer portion 12 b ₂.

As described above, the maximum measurement or the average measurement ((W₀−W₁)/2) of the side gaps 12 c is still more preferably larger than about 30 μm and less than about 90 μm, for example. When the maximum measurement or the average measurement ((W₀−W₁)/2) of the side gaps 12 c is larger than about 30 μm, the occurrence of cracks (delamination) is significantly reduced or prevented in a stable manner at the boundary between the inner layer portion 11 m and the inner portion 12 b ₂₁. In the case where the maximum measurement or the average measurement ((W₀−W₁)/2) of the side gaps 12 c is about 90 μm or more, the electrostatic capacitance of the multilayer ceramic capacitor 10 becomes too small, and it is not preferable. In other words, in the case where the maximum measurement or the average measurement ((W₀−W₁)/2) of the side gaps 12 c is less than about 90 μm, the electrostatic capacitance of the multilayer ceramic capacitor 10 is secured.

As described above, the thickness T_(i) of the inner layer portion 11 m in the stacking direction of the multilayer body 11 is larger than the width measurement W₁ of the inner layer portion 11 m, in which the plurality of conductive layers 13 are present in the widthwise direction W of the multilayer body 11. Further, the thickness T₁ of the inner layer portion 11 m in the stacking direction of the multilayer body 11 preferably is larger than the width of the multilayer body 11.

As will be described below, the boundary portion 12 z of the outer portion 12 b ₂₂ with the inner portion 12 b ₂₁ improves the sticking force between the outer portion 12 b ₂₂ and the inner portion 12 b ₂₁. Thus, even if the adhesiveness among the first dielectric layers 12 x present at the side gaps 12 c decreases due to the thicker inner layer portion 11 m, the occurrence of cracks (delamination) is significantly reduced or prevented at the boundary between the outer portion 12 b ₂₂ and the inner portion 12 b ₂₁. Accordingly the contraction force due to the thermal contraction of the outer portion 12 b ₂₂ is allowed to act on the inner portion 12 b ₂₁. This makes it possible to alleviate the internal stress applied to the boundary between the inner layer portion 11 m and the inner portion 12 b ₂₁ due to the difference in thermal contraction ratio between the conductive layer and the dielectric layer at the time of firing, and significantly reduce or prevent the occurrence of cracks (delamination) at the boundary between the inner layer portion 11 m and the inner portion 12 b ₂₁.

As described above, each layer of the second dielectric layer 12 y and the plurality of the first dielectric layers 12 x includes barium titanate as the primary component. The adhesiveness between the inner portion 12 b ₂₁ and the outer portion 12 b ₂₂ preferably is improved by forming close chemical bonding at the boundary between the inner portion 12 b ₂₁ and the outer portion 12 b ₂₂. As a result, the occurrence of cracks (delamination) is significantly reduced or prevented at the boundary between the inner portion 12 b ₂₁ and the outer portion 12 b ₂₂.

As described above, the boundary portion 12 z of the outer portion 12 b ₂₂ with the inner portion 12 b ₂₁ has a larger Si content than the middle portion 12 m of the outer portion 12 b ₂₂. Further, the top layer portion 12 s of the outer portion 12 b ₂₂ on the second principle surface 112 side has a larger Si content compared to the middle portion 12 m of the outer portion 12 b ₂₂.

Now, a method is described for increasing Si content at each one of the boundary portion 12 z and the top surface portion 12 s of the outer portion 12 b ₂₂, compared to the middle portion 12 m of the outer portion 12 b ₂₂. When the temperature and gaseous atmosphere at the time firing of the multilayer ceramic capacitor 10 are set in such a way that Si segregates from grain boundaries of ceramic articles, the grain growth of ceramic particles progresses in the outer portion 12 b ₂₂ that has a larger Si content, and Si segregates from grain boundaries of coarsened ceramic particles. Segregated Si moves along the grain boundaries of ceramic particles and accumulates at each one of the boundary portion 12 z and the top surface portion 12 s of the outer portion 12 b ₂₂. As a result, the Si content at each one of the boundary portion 12 z and the top surface portion 12 s of the outer portion 12 b ₂₂ becomes larger than that of the middle portion 12 m of the outer portion 12 b ₂₂.

In the case where the boundary portion 12 z of the outer portion 12 b ₂₂ with the inner portion 12 b ₂₁ has a larger Si content than a middle portion 12 m of the outer portion 12 b ₂₂, the sticking force between the outer portion 12 b ₂₂ and the inner portion 12 b ₂₁ is improved. The reason may be that Si, which has moved along the grain boundaries of ceramic particles as described above, fills a minute void that is abundantly present in the boundary between the outer portion 12 b ₂₂ and the inner portion 12 b ₂₁, thus connecting the outer portion 12 b ₂₂ and the inner portion 12 b ₂₁ together. Thus, it is considered that the concentration of segregated Si at the boundary portion 12 z is promoted or, conversely, the sticking force between the outer portion 12 b ₂₂ and the inner portion 12 b ₂₁ is improved by separately performing the formation of the inner portion 12 b ₂₁ and the formation of the outer portion 12 b ₂₂ and allowing the minute voids to be formed at the boundary between the inner portion 12 b ₂₁ and the outer portion 12 b ₂₂.

In the case where the top surface portion 12 s of the outer portion 12 b ₂₂ at the second principle surface 112 side has a larger Si content amount than the middle portion 12 m of the outer portion 12 b ₂₂, a decline in mechanical strength of the multilayer body 11 at the time of forming the outer electrode 14 is significantly reduced or prevented. The reason is that the mechanical strength of the multilayer body 11 decreases when a glass component contained in the outer electrode 14 reacts with a ceramic dielectric material of the multilayer body 11 at the time of forming the outer electrode 14. In this case, the multilayer body 11 is prone to crack that starts from an end portion of contact portion with the outer electrode 14 on a center side of the multilayer body 11 when the multilayer ceramic capacitor 10 receives an external force during mounting or after the mounting. In the case where the outer portion 12 b ₂₂ has a larger Si content amount, the reaction between the glass component contained in the outer electrode 14 and the ceramic dielectric material of the multilayer body 11 is significantly reduced or prevented. As a result, the decline in mechanical strength of the multilayer body 11 at the time of forming the outer electrode 14 is significantly reduced or prevented.

In the case where a rare earth compound is added to the primary component that is the perovskite type compound represented as ABO₃ at each one of the plurality of dielectric layers 12, the molar ratio of the rare earth compound relative to Ti is preferably higher in the materials of each one of the partial set of the first dielectric layers 12 x included in the inner layer portion 11 m and the first dielectric layer 12 x forming the inner portion 12 b ₂₁, compared to that of the materials of the second dielectric layer 12 y of the outer portion 12 b ₂₂. In other words, the inner layer portion 11 m and the inner portion 12 b ₂₁ preferably contain a higher amount of the rare earth element than the outer portion 12 b ₂₂.

As the rare earth element, Dy, Gd, Y, La or the like may be added to increase functionality of the multilayer ceramic capacitor 10, for example. Specifically, the addition of the rare earth element stabilizes a capacitance temperature characteristic and prolongs a high temperature load life of insulating resistance in the multilayer ceramic capacitor 10.

The rare earth element is, however, prone to concentrate at grain boundaries of ceramic particles or segregation layers, and has the property that it easily be eluted with water-soluble flux. Thus, in some cases, a ceramic component containing the rare earth element may be eluted with an organic acid such as adipic acid or the like, which is included in the water-soluble flux for use in soldering at the time of mounting the multilayer ceramic capacitor 10. In such cases, cracking may occur at the outer layer of an embrittled multilayer body from which ceramic components are eluted.

Accordingly, the molar ratio of the rare earth element relative to Ti in the materials of each one of the partial set of the first dielectric layers 12 x included in the inner layer portion 11 m and the first dielectric layer 12 x of the inner portion 12 b ₂₁ is preferably about 0.003 or more, and the molar ratio of the rare earth element relative to Ti in the materials of the second dielectric layer 12 y of the outer portion 12 b ₂₂ is preferably less than about 0.003, for example.

In the case where the molar ratio of the rare earth element relative to Ti preferably is about 0.003 or more in the materials of the first dielectric layer 12 x included in the inner layer portion 11 m, the capacitance temperature characteristic is stabilized and the high temperature load life of insulating resistance is prolonged in the multilayer ceramic capacitor 10.

In the case where the molar ratio of the rare earth element relative to Ti preferably is less than about 0.003 in the materials of the second dielectric layer 12 y of the outer portion 12 b ₂₂, the occurrence of cracks at the outer portion 12 b ₂₂, which is due to elution of ceramic components from the outer portion 12 b ₂₂ and embrittlement of the outer portion 12 b ₂₂, is significantly reduced or prevented. The foregoing features and their effects are confirmed by experiments performed with different Dy contents. Here, Dy is used as one example of the rare earth element. Similar effects are also confirmed in cases where Gd, Y, or La is used in place of Dy.

In the case where a Mn compound is added to the primary component that is the perovskite type compound represented as ABO₃ at each one of the plurality of dielectric layers 12, the molar ratio of Mn relative to Ti is preferably higher in the materials of each one of the partial set of the first dielectric layers 12 x included in the inner layer portion 11 m, the first dielectric layer 12 x of the first outer layer portion 12 b ₁, and the first dielectric layer 12 x of the inner portion 12 b ₂₁, compared to that of the materials of the second dielectric layer 12 y of the outer portion 12 b ₂₂. In other words, the inner layer portion 11 m and the inner portion 12 b ₂₁ preferably contain more Mn than the outer portion 12 b ₂₂.

Color becomes brighter in the case where the dielectric layer has a smaller Mn content. Thus, in the case where each one of the inner layer portion 11 m, the first outer layer portion 12 b ₁, and the inner portion 12 b ₂₁ contains more Mn than the outer portion 12 b ₂₂, the color of the outer portion 12 b ₂₂ becomes brighter compared to the color of each one of the inner layer portion 11 m, the first outer layer portion 12 b ₁, and the inner portion 12 b ₂₁. This makes it possible to facilitate visual discrimination between the first principle surface 111 and the second principle surface 112 of the multilayer ceramic capacitor 10.

Thus, relative positions of the first principle surface 111 and the second principle surface 112 of the multilayer ceramic capacitor 10 may be identified by observing the multilayer ceramic capacitor 10 with an image capturing camera or the like. This makes it possible to align the position of the multilayer ceramic capacitor 10 automatically in such a way that the second principle surface 112 becomes a mounting surface at the time of mounting the multilayer ceramic capacitor 10.

For example, the molar ratio of Mn relative to Ti in the materials of each one of the partial set of the first dielectric layers 12 x included in the inner layer portion 11 m, the first dielectric layer 12 x of the first outer layer portion 12 b ₁, and the first dielectric layer 12 x of the inner portion 12 b ₂₁ is preferably about 0.0008 or more, and the molar ratio of Mn relative to Ti in the materials of the second dielectric layer 12 y of the outer portion 12 b ₂₂ is preferably less than about 0.0008, for example. The foregoing features and their effects are confirmed by experiments performed with different Mn contents.

Next, a component-mounted body in which the multilayer ceramic capacitor 10 according to the present preferred embodiment is mounted on a component-receiving body is described with reference to the drawings.

FIG. 10 is a cross sectional view illustrating a structure of a multilayer ceramic capacitor mounted body according to the preferred embodiment 1 of the present invention. As illustrated in FIG. 10, a multilayer ceramic capacitor mounted body 10 x according to the preferred embodiment 1 of the present invention includes a multilayer ceramic capacitor 10 and a component-receiving body 1 on which the multilayer ceramic capacitor 10 is mounted, such as a circuit board or the like. The multilayer ceramic capacitor 10 is mounted on the component-receiving body 1 in such a way that the second principle surface 112 is disposed at the component-receiving body 1 side.

Specifically, the component-receiving body 1 includes a pair of lands 20 on its top surface, and the lands 20 are arranged at intervals. Each one of the pair of outer electrodes of the multilayer ceramic capacitor 10 is electrically connected to a corresponding one of the pair of lands 20 via solder 30 that defines and serves as a bonding agent. The bonding agent is not limited to solder, and may be any material capable of joining the pair of outer electrodes 14 and the pair of lands 20 mechanically and electrically.

A width measurement W_(L) of each one of the pair of lands 20 is less than the width measurement W₀ of the multilayer body 11. The width measurement W_(L) of each one of the pair of lands 20 is preferably less than the width measurement W₁ of the inner layer portion 11 m.

In the case where the width measurement W_(L) of each one of the pair of lands 20 is less than the width measurement W₀ of the multilayer body 11, each one of the pair of outer electrodes receives compressive stress from the solder 30 in the widthwise direction W of the multilayer body 11. The compressive stress applied to the pair of outer electrodes 14 also applies to the inner portion 12 b ₂₁ via the outer portion 12 b ₂₂. This makes it possible to alleviate internal stress applied to a boundary between the inner layer portion 11 m and the second outer layer portion 12 b ₂, and significantly reduce or prevent the occurrence of cracks (delamination) at the boundary between the inner layer portion 11 m and the second outer layer portion 12 b ₂.

In the case where the width measurement W_(L) of each one of the pair of lands 20 is less than the width measurement W₁ of the inner layer portion 11 m, the compressive stress to be applied to the inner portion 12 b ₂₁ via the outer portion 12 b ₂₂ increases, and the internal stress to be applied to the boundary between the inner layer portion 11 m and the second outer layer portion 12 b ₂ is further alleviated. This makes it possible to significantly reduce or prevent the occurrence of cracks (delamination) at the boundary between the inner layer portion 11 m and the second outer layer portion 12 b ₂.

Next, a multilayer ceramic capacitor array including a plurality of multilayer ceramic capacitors 10 according to the present preferred embodiment is described with reference to the drawings.

FIG. 11 is a plan view illustrating a structure of a multilayer ceramic capacitor array according to the preferred embodiment 1 of the present invention. FIG. 12 is a cross sectional view of the multilayer ceramic capacitor array of FIG. 11 viewed from a line XII-XII arrow direction.

As illustrated in FIGS. 11 and 12, a multilayer ceramic capacitor array 10 s according to the preferred embodiment 1 of the present invention includes a plurality of multilayer ceramic capacitors 10, an elongated carrier tape 5 in which a plurality of depressed portions 5 h are arranged at intervals to respectively store the plurality of multilayer ceramic capacitors 10, and a packaging body 4 including a cover tape 6 configured to cover the plurality of depressed portions 5 h by attaching to the carrier tape 5. The plurality of multilayer ceramic capacitors 10 is stored inside respective ones of the plurality of depressed portions 5 h in such a way that the second principle surface 112 is disposed on a bottom 5 b side of each depressed portion 5 h.

A plurality of multilayer ceramic capacitors 10 to be included in the multilayer ceramic capacitor array 10 s is picked up from the packaging body 4 piece by piece and mounted on a component-receiving body 1. Specifically, in a state where the cover tape 6 is peeled off from the carrier tape 5, the multilayer ceramic capacitor 10 is picked up from the carrier tape 5 piece by piece by holding the multilayer ceramic capacitor 10 by suction at the first principle surface 111 side, and then mounted on the component-receiving body 1. As a result, the multilayer ceramic capacitor 10 is mounted on the component-receiving body 1 in such a way that the second principle surface 112 of the multilayer ceramic capacitor 10 is disposed at the component-receiving body 1 side.

In other words, the multilayer ceramic capacitor mounted body 10 x according to the preferred embodiment 1 of the present invention may be easily fabricated by using the multilayer ceramic capacitor array 10 s according to the preferred embodiment 1 of the present invention.

Next, a multilayer ceramic capacitor according to preferred embodiment 2 of the present invention is described. It should be noted that the multilayer ceramic capacitor according to the preferred embodiment 2 of the present invention differs from the multilayer ceramic capacitor according to the preferred embodiment 1 only in shape of a boundary portion between an outer portion and an inner portion of multilayer body. Thus, the description regarding the other elements will not be repeated.

Preferred Embodiment 2

The shape of a boundary portion between an outer portion and an inner portion of multilayer body of the multilayer ceramic capacitor according to the preferred embodiment 2 of the present invention is a shape rendered by a mother sheet group pressure-bonding method. Thus, first, the mother sheet group pressure-bonding method according to the present preferred embodiment is described.

FIG. 13 is a cross sectional view illustrating a state where mother sheet groups of the multilayer ceramic capacitors according to the preferred embodiment 2 of the present invention are being pressure-bonded. FIG. 13 illustrates the same cross sectional view as in FIG. 8. FIG. 13 illustrates only a portion that corresponds to two of partial multilayer bodies 11 p.

As illustrated in FIG. 13, in the present preferred embodiment, a plurality of mother sheets defining a first outer layer portion 12 b ₁, a plurality of mother sheets defining an inner layer portion 11 m, and a plurality of mother sheets defining an inner portion 12 b ₂₁ are stacked in this order to form mother sheet groups.

The mother sheet groups placed on a base 90 is being compressed and pressure-bonded by pressing a die plate 91 and a rubber 93 attached to a bottom surface of the die plate 91 from the side of the mother sheets forming the inner portion 12 b ₂₁ along the stacking direction of the mother sheet group as denoted by an arrow 92.

In the mother sheet group, a stacking density at a location corresponding to the inner layer portion 11 m is higher than a stacking density at a location corresponding to a side gap 12 c. Thus, the rubber 93 pressed down upon the mother sheet group convexly bulges out downward due to flow deformation toward the location corresponding to the side gap 12 c from the location corresponding to the inner layer portion 11 m as denoted by dotted lines 93 s in FIG. 13. This allows the mother sheets to be pressure-bonded to each other at the location corresponding to the side gap 12 c of the mother sheet group.

FIG. 14 is a cross sectional view illustrating a halfway state where the mother sheet group thus pressured-bonded and a plurality of second ceramic green sheets are being pressure-bonded. FIG. 14 illustrates only a portion that corresponds to two of soft multilayer bodies 11 q. As illustrated in FIG. 14, the mother sheet group that is pressure-bonded and the plurality of second ceramic green sheets are being compressed and pressure-bonded by pressing down the die plate 91 from the side of the mother sheets of the outer portion 12 b ₂₂ along the stacking direction of the mother sheet group as denoted by the arrow 92. This completes the fabrication of a mother multilayer body.

FIG. 15 is a cross sectional view illustrating a state where the mother multilayer body is cut. FIG. 15 illustrates only a portion that corresponds to two of the soft multilayer bodies 11 q. As illustrated in FIG. 15, the plurality of second ceramic green sheets follows the shape of the top surface of the pressure-bonded mother sheet group, and convexly bulges out downward at the location corresponding to the side gap 12 c due to flow deformation toward the location corresponding to the side gap 12 c from the location corresponding to the inner layer portion 11 m.

Accordingly, a boundary portion 12 z of the outer portion 12 b ₂₂ with the inner portion 12 b ₂₁ includes curved portions 12 zw protruding downward at the locations corresponding to the side gaps 12 c in the widthwise direction W of the multilayer body 11.

The mother multilayer body is cut at a cut line CL and separated to define a plurality of the soft multilayer bodies 11 q. Subsequent steps after the step described above are similar to those in the fabrication method of the multilayer ceramic capacitor 10 according to the preferred embodiment 1.

In the multilayer ceramic capacitor according to the present preferred embodiment, the adhesiveness among the first dielectric layers 12 x present at the side gap 12 c is improved. As a result, the occurrence of cracks (delamination) is significantly reduced or prevented at the first dielectric layers 12 x present at the side gaps 12 c.

Further in the case where the boundary portion 12 z of the outer portion 12 b ₂₂ with the inner portion 12 b ₂₁ includes the curved portions 12 zw protruding downward at the locations corresponding to the side gaps 12 c in the widthwise direction W of the multilayer body 11, the outer portion 12 b ₂₂ holds the inner portion 12 b ₂₁ between a pair of the curved portions 12 zw. This allows the contraction force of the outer portion 12 b ₂₂ to apply effectively to the inner portion 12 b ₂₁. As a result, the internal stress, which is applied to the boundary between the inner layer portion 11 m and the second outer layer portion 12 b ₂ due to the difference in thermal contraction ratio between the conductive layer and the dielectric layer at the time of firing, is alleviated. This makes it possible to further reduce or prevent the occurrence of cracks (delamination) at the boundary between the inner layer portion 11 m and the second outer layer portion 12 b ₂.

Next, exemplary non-limiting experiments are described.

The exemplary non-limiting experiments evaluate effects of thickness and Si content amount at each one of the inner portion and the outer portion on reliability and crack occurrence at the time of firing of multilayer ceramic capacitor.

Exemplary Experiment 1

In the exemplary experiment 1, 21 types of multilayer ceramic capacitors, namely, comparison examples 1 to 11 and preferred embodiment examples 1 to 10 are prepared. First, conditions (design values) common for the 21 types of multilayer ceramic capacitors are described.

The thickness of the first outer layer portion is set to 40 μm, the thickness of the second outer layer portion is set to 100 μm, the thickness of the inner layer portion is set to 620 μm, the thickness of the conductive layer is set to 0.8 μm, the number of layers in the conductive layers is set to 330, and the molar ratio of Si relative to Ti in the materials of the first dielectric layer is set to 0.013.

For each one of the 21 types of multilayer ceramic capacitors including the comparison examples 1 to 11 and the preferred embodiment examples 1 to 10, the molar ratio of Si relative to Ti in the materials of the second dielectric layers of the outer portion, the thickness of the inner portion, and the thickness of the outer portion are set as in the following Table 1.

For the evaluation of crack occurrence at the time of firing of multilayer ceramic capacitor, ten pieces of multilayer ceramic capacitors are prepared for each one of the 21 types of multilayer ceramic capacitors. If any one of the ten pieces is found to have a crack occurrence, the multilayer ceramic capacitor type is evaluated as “bad”, and if none of the ten pieces is found to have a crack occurrence, the multilayer ceramic capacitor type is evaluated as “good”. Presence or absence of the occurrence of cracks is determined by grinding the individual piece to expose a WT cross section that goes through a center of multilayer body and by observing an exposed cross section with an optical microscope.

For the evaluation of reliability of multilayer ceramic capacitor, 20 pieces of multilayer ceramic capacitors are prepared for each one of the 21 types of multilayer ceramic capacitors. If any one of the 20 pieces is found to have IR value degradation, the multilayer ceramic capacitor type is evaluated as “bad”, and if none of the 20 pieces is found to have the IR value degradation, the multilayer ceramic capacitor type is evaluated as “good”.

The reliability of multilayer ceramic capacitor is evaluated by highly accelerated life test. Specifically, in an ambient temperature of 150 degrees C., a voltage of 8 V is applied to a multilayer ceramic capacitor, and the multilayer ceramic capacitor is determined to have the IR value degradation if an IR value of the multilayer ceramic capacitor reaches 10 kΩ or less within ten hours.

TABLE 1 MOLAR MOLAR RATIO OF SI RATIO OF SI DIFFERENCE IN MOLAR TO TI OF TO TI OF RATIO OF SI TO TI BETWEEN THICKNESS THICKNESS FIRST SECOND FIRST DIELECTRIC LAYER OF INNER OF OUTER DIELECTRIC DIELECTRIC AND SECOND DIELECTRIC PORTION PORTION CRACK LAYER LAYER LAYER (μm) (μm) OCCURRENCE RELIABILITY PREFERRED 0.013 0.017 0.004 10 90 GOOD GOOD EMBODIMENT EXAMPLE 1 PREFERRED 0.013 0.017 0.004 20 80 GOOD GOOD EMBODIMENT EXAMPLE 2 PREFERRED 0.013 0.017 0.004 30 70 GOOD GOOD EMBODIMENT EXAMPLE 3 PREFERRED 0.013 0.017 0.004 40 60 GOOD GOOD EMBODIMENT EXAMPLE 4 PREFERRED 0.013 0.017 0.004 50 50 GOOD GOOD EMBODIMENT EXAMPLE 5 COMPARISON 0.013 0.017 0.004 60 40 BAD GOOD EXAMPLE 1 COMPARISON 0.013 0.017 0.004 70 30 BAD GOOD EXAMPLE 2 PREFERRED 0.013 0.029 0.016 10 90 GOOD GOOD EMBODIMENT EXAMPLE 6 PREFERRED 0.013 0.029 0.016 20 80 GOOD GOOD EMBODIMENT EXAMPLE 7 PREFERRED 0.013 0.029 0.016 30 70 GOOD GOOD EMBODIMENT EXAMPLE 8 PREFERRED 0.013 0.029 0.016 40 60 GOOD GOOD EMBODIMENT EXAMPLE 9 PREFERRED 0.013 0.029 0.016 50 50 GOOD GOOD EMBODIMENT EXAMPLE 10 COMPARISON 0.013 0.029 0.016 60 40 BAD GOOD EXAMPLE 3 COMPARISON 0.013 0.029 0.016 70 30 BAD GOOD EXAMPLE 4 COMPARISON 0.013 0.033 0.020 10 90 GOOD BAD EXAMPLE 5 COMPARISON 0.013 0.033 0.020 20 80 GOOD GOOD EXAMPLE 6 COMPARISON 0.013 0.033 0.020 30 70 GOOD GOOD EXAMPLE 7 COMPARISON 0.013 0.033 0.020 40 60 GOOD GOOD EXAMPLE 8 COMPARISON 0.013 0.033 0.020 50 50 GOOD GOOD EXAMPLE 9 COMPARISON 0.013 0.033 0.020 60 40 BAD GOOD EXAMPLE 10 COMPARISON 0.013 0.033 0.020 70 30 BAD GOOD EXAMPLE 11

Table 1 summarizes evaluation results obtained by the exemplary experiment 1. As illustrated in Table 1, the occurrence of cracks at the time of firing of multilayer ceramic capacitor is significantly reduced or prevented in each one of the preferred embodiment examples 1 to 10 and the comparison examples 5 to 9, in which the thickness of the outer portion is equal to or larger than the thickness of the inner portion.

The multilayer ceramic capacitor of the comparison example 5 is found to be low in reliability. From this, it is discovered that the reliability of multilayer ceramic capacitor may decrease in the case where the molar ratio of Si relative to Ti in the materials of the second dielectric layer of the outer portion is larger than 0.029 and the thickness of the inner portion is less than 20 μm.

Next, exemplary non-limiting experiments are described that evaluate effects of the boundary portion of the outer portion with the inner portion having a higher Si content amount on the occurrence of cracks at the multilayer ceramic capacitor due to an external stress.

Exemplary Experiment 2

In the exemplary experiment 2, four types of multilayer ceramic capacitors, namely, comparison examples 12 to 13 and preferred embodiment examples 11 to 12 are prepared. First, conditions (design values) common for the four types of multilayer ceramic capacitors are described.

Here, the structure of the first outer layer portion is made similar to the structure of the second outer layer portion. The thickness of the first outer layer portion is set to 100 μm, the thickness of the second outer layer portion is set to 100 μm, the thickness of the inner layer portion is set to 620 μm, the thickness of the conductive layer is set to 0.8 μm, and the number of layers in the conductive layers is set to 330.

For each one of component-mounted bodies in which the four types of multilayer ceramic capacitors, namely, the comparison examples 12 to 13 and the preferred embodiment examples 11 to 12 are respectively mounted, the molar ratio of Si relative to Ti in the materials of the first dielectric layer, the molar ratio of Si relative to Ti in the materials of the second dielectric layer of the outer portion, the thickness of the inner portion, and the thickness of the outer portion are set as in the following Table 2.

For the evaluation of crack occurrence due to an external stress in a multilayer ceramic capacitor, ten pieces of multilayer ceramic capacitor mounted bodies are prepared for each one of the four types of multilayer ceramic capacitor mounted bodies. If any one of the ten pieces of multilayer ceramic capacitor mounted bodies is found to have a crack that reaches the conductive layer, that type is evaluated as “bad”, and if none of the ten pieces of multilayer ceramic capacitor mounted bodies is found to have a crack that reaches the conductive layer, that type is evaluated as “good”.

FIG. 16 is a schematic view illustrating a state where a substrate on which a multilayer ceramic capacitor is mounted is bended in the exemplary experiment 2. As illustrated in FIG. 16, the evaluation of crack occurrence due to an external stress in a multilayer ceramic capacitor is performed by checking whether a crack occurs or not at a multilayer ceramic capacitor 10 due to an external stress that applies to the multilayer ceramic capacitor 10 when a component-receiving body 1 on which the multilayer ceramic capacitor 10 is mounted is bent by a pressing jig 8.

Specifically, the multilayer ceramic capacitor 10 is mounted on a bottom surface of a component-receiving body 1, and the pressing jig 8 is pressed against the component-receiving body 1 at a right angle from a top surface side of the component-receiving body 1 as illustrated with an arrow 8 a in FIG. 16 while supporting the component-receiving body 1 by a pair of support portions 7 at both end portions of the bottom surface of the component-receiving body 1. This causes the component-receiving body 1 to convexly curve downward. As a result, in the multilayer ceramic capacitor 10, a tensile stress is loaded on the multilayer body 11 via a pair of outer electrodes 14. Whether or not this tensile stress (external stress) causes a crack occurrence in the multilayer body 11 is checked. Presence or absence of the occurrence of cracks is determined by observing a cross section that is exposed by grinding the multilayer body with an optical microscope.

TABLE 2 MOLAR RATIO OF MOLAR RATIO OF SI TO TI OF THICKNESS OF THICKNESS OF PRESENCE OR SI TO TI OF FIRST SECOND INNER PORTION OUTER PORTION ABSENCE OF CRACK DIELECTRIC LAYER DIELECTRIC LAYER (μm) (μm) BOUNDARY OCCURRENCE PREFERRED 0.013 0.017 50 50 PRESENCE GOOD EMBODIMENT EXAMPLE 11 COMPARISON 0.017 0.017 50 50 ABSENCE BAD EXAMPLE 12 PREFERRED 0.013 0.029 50 50 PRESENCE GOOD EMBODIMENT EXAMPLE 12 COMPARISON 0.029 0.029 50 50 ABSENCE BAD EXAMPLE 13

Table 2 summarizes evaluation results obtained by the exemplary experiment 2. As illustrated in Table 2, no crack that reaches the conductive layer is found in each one of the multilayer ceramic capacitor mounted bodies in the preferred embodiment examples 11 and 12 in which the boundary portion is present in the outer portion with the inner portion having a larger Si content amount. Even in the case where the occurrence of cracks is found at the outer portion, no crack extends into the inner portion. Thus, it is conceivable that the boundary portion in the outer portion with the inner portion having a larger Si content has a function to prevent a crack from reaching the conductive layer by stopping crack growth or deflect a direction of crack growth.

The present disclosure may be effectively applicable particularly to small size multilayer ceramic capacitors in which the thickness of the second outer layer portion 12 b ₂ is about 50 μm or more, the electrostatic capacitance is about 10 μF or more, the lengthwise dimension of the multilayer body 11 is about 1.8 mm or less, and the number of stacked layers in the conductive layers 13 is about 300 or more.

In particular, of the small size multilayer ceramic capacitors, the present disclosure is more effectively applicable to multilayer ceramic capacitors in which the thickness T₁ of the inner layer portion 11 m in the stacking direction of the multilayer body 11 is larger than the width measurement W₁ of the inner layer portion 11 m in which a plurality of conductive layers 13 is present in the widthwise direction W of the multilayer body 11 and multilayer ceramic capacitors in which the thickness T₁ of the inner layer portion 11 m in the stacking direction of the multilayer body 11 is larger than the width measurement W₀ of the multilayer body 11.

Next, a non-limiting example of a method for measuring thicknesses of a dielectric layer and a conductive layer of a multilayer ceramic capacitor is described. FIG. 17 is a view illustrating an example of a magnified image of a cross section of a multilayer ceramic capacitor observed with a scanning electron microscope. FIG. 17 illustrates a portion of the multilayer ceramic capacitor that is in contact with a potting compound 9 at the second principle surface 112 side.

When measuring the thicknesses of a dielectric layer and a conductive layer of a multilayer ceramic capacitor, first, as illustrated in FIG. 17, a line Lc extending in the stacking direction of a multilayer body and going through a center of the multilayer body is drawn on a magnified image of a cross section of the multilayer ceramic capacitor observed with a scanning electron microscope. Next, a plurality of lines parallel to the line Lc is drawn at even intervals (pitch S). The pitch S may be set to about five to ten times the thickness of a dielectric layer or a conductive layer to be measured. For example, in the case where a dielectric layer having a thickness of about 1 μm is to be measured, the pitch S may be set to about 5 μm. The same number of lines is drawn on both sides of the line Lc. In other words, in total, the odd number of lines is drawn including the line Lc. FIG. 17 illustrates five lines including a line La to a line Le.

Next, the thicknesses of the dielectric layers and the conductive layers are measured on each one of the line La to the line Le. In the case where, on each one of the line La to the line Le, a conductive layer is lost and dielectric layers adjacent to this lost conductive layer are connected, or the magnified image is unclear at a measurement location, the thickness or distance is measured on another line drawn at a location further separated from the line Lc.

For example, when measuring the thickness of dielectric layer 12, as illustrated in FIG. 17, a thickness D₁ on the line La, a thickness D₂ on the line Lb, a thickness D₃ on the line Lc, a thickness D₄ on the line Ld, and a thickness D₅ on the line Le are measured, and an average value of those measured thicknesses is obtained as the thickness of dielectric layer 12.

For example, when calculating an average thickness of the plurality of dielectric layers 12 in the inner layer portion 11 m, the thickness according to the foregoing method is performed for each one of five dielectric layers 12 including a dielectric layer 12 disposed at substantially the center of the inner layer portion 11 m in the thickness direction T and two pairs of dielectric layers 12 arranged at both sides thereof. An average value of measured results is obtained as the average thickness of the plurality of dielectric layers 12 in the inner layer portion 11 m.

In the case where the plurality of dielectric layers 12 includes less than five layers, the thicknesses of all the dielectric layers 12 are measured by the foregoing method, and an average value of measured results is obtained as the average thickness of the plurality of dielectric layers 12.

In a method for measuring the length of the side gaps 12 c, grinding is performed to expose the WT cross section that goes through a center of the multilayer body 11, and the cross section thus exposed is observed with an optical microscope to measure the length of a longest side gap 12 c.

In a method for measuring the width measurement W₁ of the inner layer portion 11 m, grinding is performed to expose the WT cross section that goes through a center of the multilayer body 11. Further, in the method, the cross section thus exposed is observed with an optical microscope to measure respective widths of a conductive layer 13 arranged closest to the first principle surface 111 side, a conductive layer 13 arranged closest to the second principle surface 112 side, and a conductive layer 13 arranged closest to the center of the inner layer portion 11 m in the stacking direction. Finally, an average value of these three measurement values is calculated and obtained as the width measurement W₁.

In a method for measuring the thickness T₁ of the inner layer portion 11 m, grinding is performed to expose the WT cross section that goes through a center of the multilayer body 11, and the cross section thus exposed is observed with an optical microscope to measure the length of a line segment that goes through the center of the multilayer body 11 and connects the conductive layer 13 arranged closest to the first principle surface 111 side and the conductive layer 13 arranged closest to the second principle surface 112 side with a minimum distance.

In a method for measuring the thickness of the first outer layer portion 12 b ₁ or the second outer layer portion 12 b ₂, grinding is performed to expose the WT cross section that goes through a center of the multilayer body 11, and the cross section thus exposed is observed with an optical microscope to measure the thickness of the first outer layer portion 12 b ₁ or the second outer layer portion 12 b ₂ at a center of the multilayer body 11 in the widthwise direction.

Composition analysis of materials of the first dielectric layer 12 x or the second dielectric layer 12 y may be performed by inductively coupled plasma (ICP) emission spectroscopic analysis or with a wavelength-dispersive X-ray spectrometer (WDX). In the case where the elemental analysis is performed by ICP emission spectroscopic analysis, an analysis sample is powdered and dissolved with an acid, and a solution thus obtained is analyzed by ICP emission spectroscopic analysis to determine the composition. In the case where the elemental analysis is performed with a WDX, a multilayer body buried with resin is grinded to expose the WT cross section, and the composition is determined using the WDX attached to a scanning electron microscope (SEM).

The boundary portion of the outer portion with the inner portion having a larger Si content may be identified by grinding the multilayer body buried with resin to expose a WT cross section and by capturing a backscattering electron image of the cross section thus exposed with a scanning electron microscope (SEM) for observation. Alternatively, element mapping of the exposed cross section may be produced by using a wavelength-dispersive X-ray spectrometer (WDX) attached to a scanning electron microscope (SEM), and the boundary portion may be identified by determining the portion where Si content is large.

It is to be understood that the preferred embodiments described in the present disclosure are exemplary in all aspects and are not restrictive. It is intended that the scope of the present invention is determined by the claims, not by the description described above, and includes all variations, which come within the meaning and range of equivalency of the claims.

While preferred embodiments of the present invention have been described above, it is to be understood that variations and modifications will be apparent to those skilled in the art without departing from the scope and spirit of the present invention. The scope of the present invention, therefore, is to be determined solely by the following claims. 

What is claimed is:
 1. A multilayer ceramic capacitor comprising: a multilayer body including a plurality of dielectric layers and a plurality of conductive layers, which are stacked therein in a stacking direction, and including a first principle surface and a second principle surface that are arranged so as to be opposite to each other in the stacking direction; and a pair of outer electrodes provided on portions of a surface of the multilayer body and electrically connected to at least one of the plurality of conductive layers; wherein the multilayer body includes a first end surface and a second end surface that are arranged at opposite sides of the multilayer body and connect the first principle surface and the second principle surface, and a first side surface and a second side surface that are arranged at opposite sides of the multilayer body and connect the first principle surface and the second principle surface as well as the first end surface and the second end surface; the multilayer body further includes a first outer layer portion which is a dielectric layer arranged closest to the first principle surface, a second outer layer portion which is a dielectric layer arranged closest to the second principle surface, and an inner layer portion adjacent to both of the first outer layer portion and the second outer layer portion, the inner layer portion including a conductive layer arranged closest to the first principle surface and a conductive layer arranged closest to the second principle surface; the second outer layer portion includes an outer portion and an inner portion, the outer portion being thicker than the first outer layer portion and including the second principle surface, the inner portion being arranged between the outer portion and the inner layer portion; the dielectric layers include barium titanate as a primary component and Si as an accessory component; the outer portion has a higher Si composition ratio relative to Ti, compared to the dielectric layers included in the inner layer portion and the inner portion; and a boundary portion between the outer portion and the inner portion has a larger Si content compared to the outer portion; the dielectric layers included in the inner layer portion have a higher rare earth element composition ratio relative to Ti, compared to the outer portion; and the dielectric layers included in the inner layer portion, the first outer layer portion, and the inner portion has a higher Mn composition ratio relative to Ti, compared to the outer portion.
 2. The multilayer ceramic capacitor according to claim 1, wherein the Si composition ratio relative to Ti in the outer portion is about 0.004 higher than the Si composition ratio relative to Ti in the inner portion; the Si composition ratio relative to Ti in the outer portion is not less than about 0.013 and not larger than about 0.03; the rare earth element composition ratio relative to Ti in the dielectric layers included in the inner layer portion is about 0.003 or more, and the rare earth element composition ratio relative to Ti in the outer portion is less than about 0.003; the Mn composition ratio relative to Ti in the dielectric layers included in the inner layer portion, the first outer layer portion, and the inner portion is about 0.0008 or more; and the Mn composition ratio relative to Ti in the outer portion is about 0.0008 or less.
 3. A multilayer ceramic capacitor comprising: a multilayer body including a plurality of dielectric layers and a plurality of conductive layers, which are stacked therein in a stacking direction, and including a first principle surface and a second principle surface that are arranged so as to be opposite to each other in the stacking direction; and a pair of outer electrodes provided on portions of a surface of the multilayer body and electrically connected to at least one of the plurality of conductive layers; wherein the multilayer body includes a first end surface and a second end surface that are arranged at opposite sides of the multilayer body and connect the first principle surface and the second principle surface, and a first side surface and a second side surface that are arranged at opposite sides of the multilayer body and connect the first principle surface and the second principle surface as well as the first end surface and the second end surface; the multilayer body further includes a first outer layer portion which is a dielectric layer arranged closest to the first principle surface, a second outer layer portion which is a dielectric layer arranged closest to the second principle surface, and an inner layer portion adjacent to both of the first outer layer portion and the second outer layer portion, the inner layer portion including a conductive layer arranged closest to the first principle surface and a conductive layer arranged closest to the second principle surface; the second outer layer portion includes an outer portion and an inner portion, the outer portion being thicker than the first outer layer portion and including the second principle surface, the inner portion being arranged between the outer portion and the inner layer portion; the dielectric layers include barium titanate as a primary component and Si as an accessory component; the outer portion has a higher Si composition ratio relative to Ti, compared to the dielectric layers included in the inner layer portion and the inner portion; a boundary portion between the outer portion and the inner portion has a larger Si content compared to the outer portion; the dielectric layers included in the inner layer portion have a higher rare earth element composition ratio relative to Ti, compared to the outer portion; the dielectric layers included in the inner layer portion, the first outer layer portion, and the inner portion has a higher Mn composition ratio relative to Ti, compared to the outer portion; and the inner portion is thicker than the first outer layer portion.
 4. The multilayer ceramic capacitor according to claim 3, wherein the Si composition ratio relative to Ti in the outer portion is about 0.004 higher than the Si composition ratio relative to Ti in the inner portion; the Si composition ratio relative to Ti in the outer portion is not less than about 0.013 and not larger than about 0.03; the rare earth element composition ratio relative to Ti in the dielectric layers included in the inner layer portion is about 0.003 or more, and the rare earth element composition ratio relative to Ti in the outer portion is less than about 0.003; the Mn composition ratio relative to Ti in the dielectric layers included in the inner layer portion, the first outer layer portion, and the inner portion is about 0.0008 or more; and the Mn composition ratio relative to Ti in the outer portion is about 0.0008 or less.
 5. A multilayer ceramic capacitor comprising: a multilayer body including a plurality of dielectric layers and a plurality of conductive layers, which are stacked therein in a stacking direction, and including a first principle surface and a second principle surface that are arranged so as to be opposite to each other in the stacking direction; and a pair of outer electrodes provided on portions of a surface of the multilayer body and electrically connected to at least one of the plurality of conductive layers; wherein the multilayer body includes a first end surface and a second end surface that are arranged at opposite sides of the multilayer body and connect the first principle surface and the second principle surface, and a first side surface and a second side surface that are arranged at opposite sides of the multilayer body and connect the first principle surface and the second principle surface as well as the first end surface and the second end surface; the multilayer body further includes a first outer layer portion which is a dielectric layer arranged closest to the first principle surface, a second outer layer portion which is a dielectric layer arranged closest to the second principle surface, and an inner layer portion adjacent to both of the first outer layer portion and the second outer layer portion, the inner layer portion including a conductive layer arranged closest to the first principle surface and a conductive layer arranged closest to the second principle surface; the second outer layer portion includes an outer portion and an inner portion, the outer portion being thicker than the first outer layer portion and including the second principle surface, the inner portion being arranged between the outer portion and the inner layer portion; the dielectric layers include barium titanate as a primary component and Si as an accessory component; the outer portion has a higher Si composition ratio relative to Ti, compared to the dielectric layers included in the inner layer portion and the inner portion; a boundary portion between the outer portion and the inner portion has a larger Si content compared to the outer portion; the dielectric layers included in the inner layer portion have a higher rare earth element composition ratio relative to Ti, compared to the outer portion; the dielectric layers included in the inner layer portion, the first outer layer portion, and the inner portion has a higher Mn composition ratio relative to Ti, compared to the outer portion; and a thickness of the inner layer portion in the stacking direction is larger than a width of the conductive layer nearest to the second outer layer portion.
 6. The multilayer ceramic capacitor according to claim 5, wherein the inner portion is thicker than the first outer layer portion.
 7. The multilayer ceramic capacitor according to claim 6, wherein the Si composition ratio relative to Ti in the outer portion is about 0.004 higher than the Si composition ratio relative to Ti in the inner portion; the Si composition ratio relative to Ti in the outer portion is not less than about 0.013 and not larger than about 0.03; the rare earth element composition ratio relative to Ti in the dielectric layers included in the inner layer portion is about 0.003 or more, and the rare earth element composition ratio relative to Ti in the outer portion is less than about 0.003; the Mn composition ratio relative to Ti in the dielectric layers included in the inner layer portion, the first outer layer portion, and the inner portion is about 0.0008 or more; and the Mn composition ratio relative to Ti in the outer portion is about 0.0008 or less. 